Stereochemistry of the Conversion of 2-Phenoxyethanol into Phenol and Acetaldehyde by Acetobacterium sp
نویسندگان
چکیده
by Giovanna Speranza*a), Britta Muellerb), Maximilian Orlandia), Carlo F. Morellia), Paolo Manittoa), and Bernhard Schinkb) a) Dipartimento di Chimica Organica e Industriale, Universita¡ degli Studi di Milano, via Venezian 21, I-20133 Milano (phone: 390250314097; fax: 390250314072; e-mail : [email protected]) b) Fakult‰t f ̧r Biologie, Universit‰t Konstanz, Universit‰tsstrasse 10, D-78457 Konstanz
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Mechanism of anaerobic ether cleavage: conversion of 2-phenoxyethanol to phenol and acetaldehyde by Acetobacterium sp.
2-Phenoxyethanol is converted into phenol and acetate by a strictly anaerobic Gram-positive bacterium, Acetobacterium strain LuPhet1. Acetate results from oxidation of acetaldehyde that is the early product of the biodegradation process (Frings, J., and Schink, B. (1994) Arch. Microbiol. 162, 199-204). Feeding experiments with resting cell suspensions and 2-phenoxyethanol bearing two deuterium ...
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